冻融循环下BFRP筋与混凝土黏结强度试验研究

为了研究冻融循环作用下BFRP筋与混凝土黏结强度,对不同冻融次数（0、10、20、40次）和不同混凝土强度等级（C30、C35、C40）共36个试件进行冻融循环试验和中心拉拔试验。试验结果表明:未经冻融循环的试件和冻融循环40次（C30）试件发生拔出破坏,其余冻融试件均发生劈裂破坏;随着混凝土强度等级提高,脱胶强度和黏结强度逐渐增加;随着冻融循环次数增加,BFRP筋与混凝土的黏结强度和峰值滑移呈现出先增加后减小的趋势,而脱胶强度随冻融循环次数增加逐渐减小。     

一种RDX基PBX炸药力学性能和本构关系研究

利用分离式霍普金森压杆(SHPB)对一种RDX基PBX炸药进行了高应变率加载试验,得到了其在不同应变率(300~1 200 s-1)范围内的力学性能,并用扫描电子显微镜(SEM)对回收样品进行了微观分析。结果表明:材料的力学性能和损伤均具有明显的应变率效应。采用含损伤的ZWT非线性黏弹性本构模型,对试验数据进行了拟合,拟合曲线和试验曲线吻合良好。     

Fabrication of high-purity HfSi2 powder via molten salt-assisted magnesium thermal reduction

In this work, high-purity HfSi₂ powders were successfully fabricated via a molten salt-assisted magnesium thermal reduction method using HfO₂ and Si as raw materials. The effects of reaction temperature and time on the formation of HfSi₂ were systemically investigated. The morphological and phase composition of as-prepared HfSi₂ powders were characterized by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, and nitrogen/oxygen determinator. The results indicated that as-obtained HfSi₂ powders possess the orthorhombic structure with approximately 6.4 μm in size and the oxygen content as low as 0.20%. This work can provide a novel route to fabricate the high-purity transition metal silicides powders.     

Experimental Validation of Reaction Rate Distributions for a SVEA-96+ BWR Assembly with Hafnium Control Blades

The accurate estimation of reactor physics parameters related to the presence of cruciform absorber blades in boiling water reactors (BWRs) is important for safety assessment and for achieving flexible operation during the cycle. Characteristics that are affected significantly include distributions of the total fission (F_tot) and ²³⁸Ucapture (C₈) rates for controlled regions. Representative experimental investigations have been performed in the framework of the LWR-PROTEUS programme. In particular, the LWRPROTEUS I-2A experiments concerned the neutronics characterisation of a SVEA-96+ BWR assembly controlled with a hafnium (Hf) blade under full-density water moderation conditions. The current paper presents the comparisons of the measured F_tot and C₈ pin-wise distributions with a variety of stochastic and deterministic calculations: (a) MCNPX2.5 using recent nuclear data libraries (JEFF-3.1, ENDF/BVI. 8, and JENDL-3.3), (b) PHOENIX4 using ENDF/B-VI.3, (c) BOXER using JEF-1, (d) CASMO₄ using JEF-2.2, and (e) HELIOS1.6 using ENDF/B-VI.1. The calculation/experiment comparisons show standard deviations from 1.2% (MCNPX2.5) up to 1.9% (BOXER) for the prediction of the F_tot distribution, the highest individual discrepancy (7.6% with BOXER) being seen close to the “Hf-vertex.” The C₈ comparisons show systematically better agreement than those of F_tot, the lowest standard deviations being 1.0% (BOXER) and the highest only 1.4% (HELIOS). In addition, sensitivity studies highlight the greater importance of modelling aspects, compared with that of nuclear data libraries, for the achievement of satisfactory and validated F_tot and C₈ predictions.     

长螺旋成孔灌注桩在邯钢435m2烧结机工程上的应用

介绍了长螺旋成孔振捣插筋后压浆工艺,该工艺是在长螺旋成孔工法的基础上增加了振捣插筋和孔底注浆两个重要环节.这种不同工艺的组合通过试验大幅度提高了单桩承载力和变形要求,并使桩身强度得到了极大的利用,该工艺具有良好的应用价值和使用前景.     

加快标准与规范修订促进高强钢筋推广应用

简要探讨了高强钢筋的生产和标准规范现状，并提出了推广高强钢筋的建议。     

Hf-based Metal-Organic Frameworks in Heterogeneous Catalysis

Among the large family of metal-organic frameworks (MOFs), Hf-based MOFs are foreseen as promising materials for practical applications due to their exceptional characteristics such as rich structure versatility and outstanding stability. This review discusses catalytic applications of Hf-MOFs since their development in 2012, and are summarized according to the location of the active site: at the hafnium node, at the linker or as a single-site chemical entity located at the hafnium node after post-synthetic functionalization. Special emphasis is made to synthetic preparation methods and catalytic performance.     

High-temperature behavior of oxide dispersion strengthening CoNiCrAlY

To fabricate oxide dispersion strengthened bond coatings, commercial Co–30wt-%Ni–20Cr–8Al–0?4Y powder was milled with 2% additions of Al₂O₃, Y₂O₃ or Y₂O₃ + HfO₂. Low-pressure plasma sprayed, free-standing specimens were oxidised in air + 10%H2O at 1100 °C both isothermally (100 h) and in 500, 1?h cycles. Dry air cyclic testing conducted at both ORNL and FZJ showed remarkably similar results. In general, the water vapour addition caused more scale spallation. Two LPPS specimens without oxide additions were tested for comparison. The specimens with 2%Al₂O₃ addition exhibited the best behaviour as the powder already contained 0?4%Y. Additions of 2%Y₂O₃ and especially 1%Y₂O₃ + 1%HfO₂ resulted in over-doping as evidenced by high mass gains and the formation of Y- and Hf-rich pegs. Scanning transmission electron microscopy of the isothermal specimens showed no Hf and/or Y segregation to the alumina scale grain boundaries in the over-doped specimens.     

Solvent extraction reaction of hafnium(IV) from strong sulfuric acid solutions with D2EHPA and PC 88A

Hafnium can be selectively extracted over zirconium from strong sulfuric acid solutions by D2EHPA or PC 88A. Solvent extraction experiments have been performed to identify the reaction of Hf from strong sulfuric acid solutions (1 to 7 M) by these two extractants. Hafnium extraction was gradually decreased and then increased again with the increase of sulfuric acid concentration. By applying a slope method, the extracted Hf species was proposed to be HfA₄·(HA)₂ by D2EHPA and Hf(HSO₄)₂A₂·(HA)₂ by PC 88A, respectively. This difference in the nature of the extracted species was verified by FT-IR spectra.     

Experimental study and code predictions of fibre reinforced polymer reinforced concrete (FRP RC) tensile members

Due to their different mechanical properties, cracking and deformability behaviour of FRP reinforced concrete (FRP RC) members is quite different from traditional steel reinforced concrete (SRC) having great incidence on their serviceability design. This paper presents and discusses the results of an experimental programme concerning concrete tension members reinforced with glass fibre reinforced polymer (GFRP) bars. The main aim of the study is to evaluate the response of GFRP reinforced concrete (GFRP RC) tension members in terms of cracking and deformations. The results show the dependence of load-deformation response and crack spacing on the reinforcement ratio. The experimental results are compared to prediction models from codes and guidelines (ACI and Eurocode 2) and the suitability of the different approaches for predicting the behaviour of tensile members is analysed and discussed.